Phase Relations in the CaO-Nd2O3-Al2O3 System in Application for Rare Earth Recycling

نویسندگان

چکیده

Abstract Phase relations in the CaO-Al 2 O 3 -Nd system were investigated temperature range between 1330°C and 1600°C using equilibration technique followed by characterization x-ray diffraction scanning electron microscopy combined with energy-dispersive spectroscopy (SEM/EDX). Melting differential thermal analysis microstructure study SEM/EDX. It was found that CaNdAlO 4 ( ? 1 ) compound melted congruently at 1808°C, while CaNdAl 7 incongruently 1766°C. The sample stability fields adjacent to lowest eutectic (CaAl + Ca Al 6 as well samples field CaAl completely 1600°C. 12 14 33 phase considered not stable anhydrous atmosphere instead of after heat treatment 1330°C. After melting formed glass. obtained results are important for selection conditions process rare earth recycling from waste permanent NdFeB magnets.

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ژورنال

عنوان ژورنال: JOM

سال: 2023

ISSN: ['1543-1851', '1047-4838']

DOI: https://doi.org/10.1007/s11837-023-05731-8